N-(3,4-Dichlorophenyl)-4-methylbenzenesulfonamide
نویسندگان
چکیده
In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment has gauche torsions with respect to the S=O bonds. The mol-ecule is bent at the S atom with a C-SO(2)-NH-C torsion angle of 64.3 (4)°. Furthermore, the conformation of the N-H bond and the meta-chloro group in the adjacent benzene ring are anti to each other. The two benzene rings are tilted relative to each other by 82.5 (1)°. In the crystal, mol-ecules are linked by pairs of N-H⋯O(S) hydrogen bonds, forming inversion dimers.
منابع مشابه
N-(2,6-Dichlorophenyl)-4-methylbenzenesulfonamide
In the title compound, C(13)H(11)Cl(2)NO(2)S, the mol-ecule is bent at the S atom with a C-SO(2)-NH-C torsion angle of -90.4 (2)°. The sulfonyl benzene and the aniline benzene rings are tilted relative to each other by 51.7 (1)°. In the crystal, mol-ecules are linked by N- H⋯O inter-actions into chains with graph-set notation C(4) along [100].
متن کاملN-(3,5-Dichlorophenyl)-4-methylbenzenesulfonamide
In the crystal structure of the title compound, C(13)H(11)Cl(2)NO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment is gauche with respect to the SO bonds. The two benzene rings are tilted by 79.6 (1)° relative to each other. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds occur.
متن کاملN-(2,3-Dichlorophenyl)-4-methylbenzenesulfonamide
The title compound, C(13)H(11)Cl(2)NO(2)S, contains two molecules in the asymmetric unit in which the dihedral angles between the benzene rings are 76.0 (1) and 79.9 (1)°. The conformations of the N-H bonds with respect to their adjacent ortho-chlorine atoms are syn. In the crystal, N-H⋯O hydrogen bonds link the molecules into dimers.
متن کامل4-Chloro-N-(3,5-dichlorophenyl)-2-methylbenzenesulfonamide
In the title compound, C(13)H(10)Cl(3)NO(2)S, torsion angle of the C-SO(2)-NH-C group in the mol-ecule is -58.57 (26)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 84.2 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.
متن کاملN-(2,4-Dichlorophenyl)-4-methylbenzenesulfonamide
The mol-ecule of the title compound, C(13)H(11)Cl(2)NO(2)S, is bent at the S atom with a C-SO(2)-NH-C torsion angle of -69.07 (16)°. The sulfonyl and aniline rings are rotated relative to each other by 53.0 (1)°. In the crystal, pairs of N-H⋯O(S) hydrogen bonds link the mol-ecules into centrosymmetric dimers.
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2010